Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations     

Roland?StalderEmail author  Stephan?Klemme  Thomas?Ludwig  Henrik?Skogby 《Contributions to Mineralogy and Petrology》2005,150(5):473-485

The incorporation of hydrogen into ferrosilite, Fe-bearing enstatite and orthopyroxene containing different trivalent cations (Cr³⁺ and Al³⁺, Cr³⁺ and Fe³⁺) was investigated experimentally at 25 kbar. Hydrogen concentration was determined by FTIR-spectroscopy on oriented crystal sections and by secondary ion mass spectroscopy, whereas Mößbauer spectroscopy and optical spectroscopy were used to characterise the valence state of Fe in orthopyroxene. Results suggest that hydrogen incorporation in ferrosilite is achieved by a similar mechanism as in pure enstatite. In Cr-bearing samples, however, hydrogen incorporation is reduced by the presence of other trivalent cations by an increased tendency to form Tschermaks substitutions, e.g. Si _T ⁴⁺ + Mg _M1 ²⁺ ? Al _T ³⁺ + Cr _M1 ³⁺ . Thus, hydrogen solubility in natural orthopyroxenes from the Earth’s mantle, containing significant amounts of Cr³⁺, Al³⁺, and Fe³⁺, may be much more limited than expected from their trivalent cation content, as a large fraction of the trivalent cations does not participate in H-incorporating reactions as 2 Mg _M1 ²⁺ ? M _M1 ³⁺ + V_M1 + H _i ⁺ .  相似文献   

Paleostress analysis of the Cretaceous rocks in the eastern margin of the Dead Sea transform, Jordan     

Abdullah A. Diabat  Mohammad Atallah  Mustafa R. Salih 《Journal of African Earth Sciences》2004,38(5):155

This paper presents the first paleostress results from fault-slip data on Cretaceous limestone at the eastern rim of the Dead Sea transform (DST) in Jordan. Stress inversion of fault-slip data is performed using an improved right dieder method, followed by rotational optimization (Delvaux, TENSOR Program). The orientation of the principal stress axes (σ₁, σ₂ and σ₃) and the ratio of the principal stress differences ( ) show two main paleostress fields marking two main stress regimes, strike-slip and extensional. The first is characterized by NNW–SSE compression and ENE–WSW extension and related to Middle Miocene-Recent sinistral movement along the Dead Sea transform and the opening of the Red Sea. The second paleostress field is a WNW–ESE compression and NNE–SSW extension restricted to the northern part of the investigated area. This stress field could be associated with the development of the Syrian Arc fold belt which started during the Turonian, or it may be due to an anticlockwise rotation of the first stress field.  相似文献   

Top-down modeling and bottom-up dynamics: Linking a fisheries-based ecosystem model with climate hypotheses in the Northern California Current   总被引：3，自引：2，他引：3  

J.C. Field  R.C. Francis  K. Aydin 《Progress in Oceanography》2006,68(2-4):238

In this paper we present results from dynamic simulations of the Northern California Current ecosystem, based on historical estimates of fishing mortality, relative fishing effort, and climate forcing. Climate can affect ecosystem productivity and dynamics both from the bottom-up (through short- and long-term variability in primary and secondary production) as well as from the top-down (through variability in the abundance and spatial distribution of key predators). We have explored how the simplistic application of climate forcing through both bottom-up and top-down mechanisms improves the fit of the model dynamics to observed population trends and reported catches for exploited components of the ecosystem. We find that using climate as either a bottom-up or a top-down forcing mechanism results in substantial improvements in model performance, such that much of the variability observed in single species models and dynamics can be replicated in a multi-species approach. Using multiple climate variables (both bottom-up and top-down) simultaneously did not provide significant improvement over a model with only one forcing. In general, results suggest that there do not appear to be strong trophic interactions among many of the longer-lived, slower-growing rockfish, roundfish and flatfish in this ecosystem, although strong interactions were observed in shrimp, salmon and small flatfish populations where high turnover and predation rates have been coupled with substantial changes in many predator populations over the last 40 years.  相似文献   

Sedimentation rates off SW Africa since the late Miocene deciphered from spectral analyses of borehole and GRA bulk density profiles: ODP Sites 1081–1084     

Thomas J. Gorgas  Roy H. Wilkens   《Marine Geology》2002,180(1-4):29-47

Sedimentation rates (SRs) off SW Africa were calculated by performing spectral analyses in the depth domain on borehole and gamma-ray attenuation (GRA) bulk density data from ODP Sites 1081–1084. Inversion and integration of SRs versus depth from spectral analysis yielded detailed SR profiles in the time domain. Our technique allowed the detection of excursions in calculated SRs that not only often differed from those established through coarse-scaled biostratigraphic data, but also revealed a greater regional variability in the sediment accumulation over time. High-resolution bulk density data exhibited distinct periodicity in the waveband of Milankovitch cycles (precession at 19–23 kyr; obliquity at 41 kyr; eccentricity at 100 kyr). The pronounced Milankovitch cyclicity suggests that climate variability and trends in SRs along the Benguela Current System (BCS) were responding to insolation patterns during the past 6 Myr. We find relatively low SRs when evolutive amplitude spectra are dominated by obliquity and eccentricity periods. In contrast, significant SR peaks at all sites often occur when strong precessional amplitudes coexist with obliquity and eccentricity cycles. Episodes of high SRs often coincide with peaks in organic carbon mass accumulation rates (MAR C_org) and reduced sea surface temperature (SST) in the southern Walvis Basin, which have been associated with increased regional upwelling. This suggests that the high SRs reflect high productivity (high MAR C_org) attributed to strong wind and upwelling intensity during cool climate periods (low SSTs) in accordance with orbital forcing patterns observed in our spectra.  相似文献   

Deep and Bottom Currents in the Challenger Deep,Mariana Trench,Measured with Super-Deep Current Meters   总被引：3，自引：0，他引：3  

Keisuke?TairaEmail author  Shoji?Kitagawa  Toru?Yamashiro  Daigo?Yanagimoto 《Journal of Oceanography》2004,60(6):919-926

The bottom currents in the Challenger Deep, the deepest in the world, were measured with super-deep current meters moored at 11°22′ N and 142°35′ E, where the depth is 10915 m. Three current meters were set at 9687 m, 10489 m and 10890 m at the station in the center of the Challenger Deep for 442 days from 1 August 1995 to 16 October 1996. Although rotor revolutions in 60 minutes of recording interval were zero for 37.5% of the time, the maximum current at the deepest layer of 10890 m was 8.1 cm s⁻¹, being composed of tidal currents, inertia motion and long period variations. Two current meters were set at 6608 m and 7009 m at a station 24.9 km north of the center for 443 days from 31 July 1995 to 16 October 1996, and two current meters at 6214 m and 6615 m at a station 40.9 km south of the center for 441 days from 2 August 1995 to 16 October 1996. The mean flow at 7009 m depth at the northern station was 0.7 cm s⁻¹ to 240°T, and that at 6615 m depth at the southern station was 0.5 cm s⁻¹ to 267°T. A westward mean flow prevailed at the stations, and no cyclonic circulation with mean flows of the opposite directions was observed in the Mariana Trench at a longitude of 142°35′ E. Power spectra of daily mean currents showed three spectral peaks at periods of 100 days, 28–32 days and 14–15 days. The peak at 100 day period was common to the power spectra.  相似文献   

Ocean basins near the Scotia–Antarctic plate boundary: Influence of tectonics and paleoceanography on the Cenozoic deposits     

A. Maldonado  F. Bohoyo  J. Galindo-Zaldívar  J. Hernández-Molina  A. Jabaloy  F. J. Lobo  J. Rodríguez-Fernández  E. Suriñach  J. T. Vázquez 《Marine Geophysical Researches》2006,27(2):83-107

The distribution of seismic units in deposits of the basins near the Antarctic–Scotia plate boundary is described based on the analysis of multichannel seismic reflection profiles. Five main seismic units are identified. The units are bounded by high-amplitude continuous reflectors, named a to d from top to bottom. The two older units are of different age and seismic facies in each basin and were generally deposited during active rifting and seafloor spreading. The three youngest units (3 to 1) exhibit, in contrast, rather similar seismic facies and can be correlated at a regional scale. The deposits are types of contourite drift that resulted from the interplay between the northeastward flow of Weddell Sea Bottom Water (WSBW) and the complex bathymetry in the northern Weddell Sea, and from the influence of the Antarctic Circumpolar Current and the WSBW in the Scotia Sea. A major paleoceanographic event was recorded by Reflector c, during the Middle Miocene, which represents the connection between the Scotia Sea and the Weddell Sea after the opening of Jane Basin. Unit 3 (tentatively dated ∼Middle to Late Miocene) shows the initial incursions of the WSBW into the Scotia Sea, which influenced a northward progradational pattern, in contrast to the underlying deposits. The age attributed to Reflector b is coincident with the end of spreading at the West Scotia Ridge (∼6.4 Ma). Unit 2 (dated ∼Late Miocene to Early Pliocene) includes abundant high-energy, sheeted deposits in the northern Weddell Sea, which may reflect a higher production of WSBW as a result of the advance of the West Antarctic ice-sheet onto the continental shelf. Reflector a represents the last major regional paleoceanographic change. The timing of this event (∼3.5–3.8 Ma) coincides with the end of spreading at the Phoenix–Antarctic Ridge, but may be also correlated with global events such as initiation of the permanent Northern Hemisphere ice-sheet and a major sea level drop. Unit 1 (dated ∼Late Pliocene to Recent) is characterized by abundant chaotic, high-energy sheeted deposits, in addition to a variety of contourites, which suggest intensified deep-water production. Units 1 and 2 show, in addition, a cyclic pattern, more abundant wavy deposits and the development of internal unconformities, all of which attest to alternating periods of increased bottom current energy.  相似文献   

An analytical diagnostic model of the Antarctic Circumpolar Current     

Qiao Fangli  Zhang Qinghu  He Wen 《海洋学报(英文版)》1996,15(1):9-17

ＡｎａｎａｌｙｔｉｃａｌｄｉａｇｎｏｓｔｉｃｍｏｄｅｌｏｆｔｈｅＡｎｔａｒｃｔｉｃＣｉｒｃｕｍｐｏｌａｒＣｕｒｒｅｎｔ￥ＱｉａｏＦａｎｇｌｉ；ＺｈａｎｇＱｉｎｇｈｕａａｎｄＨｅＷｅｎ（ＲｅｃｅｉｖｅｄＮｏｖｅｍｂｅｒ１０，１９９５；ａｃｃｅｐｔｅｄＮ...  相似文献   

Biomass and productivity distributions and their variability in the Barents Sea   总被引：8，自引：0，他引：8  

Sakshaug  Egil 《ICES Journal of Marine Science》1997,54(3):341-350

  相似文献   

An inverse model of the large scale circulation in the South Indian Ocean   总被引：1，自引：0，他引：1  

E. Sultan  H. Mercier 《Progress in Oceanography》2007,74(1):71-94

An overview of the large-scale circulation of the South Indian Ocean (SIO) (10°S-70°S/20°E-120°E) is proposed based on historical hydrographic data (1903-1996) synthesized with a finite-difference inverse model. The in situ density, potential temperature and salinity fields of selected hydrographic stations are projected on the basis of EOFs. Then the EOF coefficients (the projected values) are interpolated on the model grid (1° in latitude, 2° in longitude) using an objective analysis whose spatial correlation functions are fitted to the data set. The resulting fields are the input of the inverse model. This procedure filters out the small-scale features. Twelve modes are needed to keep the vertical structures of the fields but the first three modes are sufficient to reproduce the large-scale horizontal features of the SIO: the Subtropical Gyre, the Weddell Gyre, the different branches of the Antarctic Circumpolar Current.The dynamics is steady state. The estimated circulation is in geostrophic balance and satisfies mass, heat and potential vorticity conservation. The wind and air-sea heat forcing are annual means from ERS1 and ECMWF, respectively.The main features of the various current systems of the SIO are quantified and reveal topographic control of the deep and bottom circulation. The cyclonic Weddell Gyre, mainly barotropic, transports 45 Sv (1 Sv = 10⁶m³/s), and has an eastern extension limited by the southern part of the Antarctic Circumpolar Current.The bottom circulation north of 50°S is complex. The Deep Western Boundary Currents are identified as well as cyclonic recirculations. South east of the Kerguelen Plateau, the bottom circulation is in good agreement with previous water mass analysis. The comparison between some recent regional analysis and the inverse estimation is limited by the model resolution and lack of deep data.The meridional overturning circulation (MOC) is estimated from the finite difference inverse model. Between 26°S and 32°S the reversal of the current deepens and reaches 1400 m at 32°S. The major part of the deep meridional transport at 32°S is located between the African coast and the Madagascar Ridge, carried by the Agulhas Undercurrent. The mean value for this meridional thermohaline recirculation is 8.8 ± 4.4 Sv between 26°S and 32°S. The Agulhas Undercurrent (11 Sv) is associated with a weak Agulhas Current (55 Sv). The MOC is thus trapped in the western margin of the Southwest Indian Ridge. The corresponding vertical velocity along 32°S between 30°E and 42°E is 7.2 × 10⁻⁵ ± 8.9 × 10⁻⁵ cm s⁻¹. The net meridional heat flux represents −0.53 PW at 18°S and −0.33 PW at 32°S (negative values for southward transports). The intensity of the meridional heat flux is linked to the intensity of the Agulhas Current and to the vertical mixing.  相似文献   

The circulation, water masses and sea-ice of Baffin Bay   总被引：2，自引：0，他引：2  

Charles C.L Tang  Charles K. Ross  Tom Yao  Brian Petrie  Brendan M. DeTracey  Ewa Dunlap 《Progress in Oceanography》2004,63(4):183-228

The oceanographic, meteorological and sea-ice conditions in Baffin Bay are studied using historical hydrographic, satellite and meteorological data, and a set of current meter data from a mooring program of the Bedford Institute of Oceanography. Baffin Bay is partially covered by sea-ice all year except August and September. The interannual variation of the ice extent is shown to be correlated with winter air temperature. Available hydrographic data were used to study the water masses and the horizontal and vertical distribution of temperature/salinity. Three water masses can be identified – Arctic Water in the upper 100–300 m of all regions except the southeast, West Greenland Intermediate Water at 300–800 m in most of the interior of Baffin Bay, and Deep Baffin Bay Water in all regions below 1200 m. The temperature and salinity in Baffin Bay have limited seasonal variability except in the upper 300 m of eastern Davis Strait, northern Baffin Bay and the mouth of Lancaster Sound. Summer data have a temperature minimum at 100 m, which suggests winter convection does not penetrate deeper than this depth. Current meter data and results of a circulation model indicate that the mean circulation is cyclonic. The seasonal variation of the currents is complex. Overall, summer and fall tend to have stronger currents than winter and spring at all depths. Among the different regions, the largest seasonal variation occurs at the mouth of Lancaster Sound and the Baffin Island slope. Model generated velocity fields show a basic agreement with the observed currents, and indicate strong topographic control in the vicinity of Davis Strait and on the Greenland shelves. The model also produces a southward counter current on the Greenland slope, which may explain the observed high horizontal shears over the Greenland slope. Estimates of the volume and fresh water transports through Lancaster, Jones and Smith Sounds are reviewed. Transports through Davis Strait are computed from the current meter data. The balance of freshwater budget and sensitivity of the thermohaline circulation to freshwater transport are discussed.  相似文献